Argentometric titration. Definition: The process of determining the quantity of a sample by adding measured increments of a titrant until the end-point, at which. automatic titrator will be used to perform the titration, and to obtain the titration curve. Background. Argentometric Titrations. In order for a titrimetric method to be . A titration in which Ag+ is the titrant is called an argentometric titration. Table provides a list of several typical precipitation titrations.

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In analytical chemistryargentometry is a type of titration involving the silver I ion. As a result, the end point is always later than the equivalence point. A typical calculation is shown in the following example. Although precipitation titrimetry is rarely listed as a standard method of analysis, it may argentimetric be useful as a secondary analytical method for verifying other analytical methods.

Carbonates and phosphates precipitate with silver, and need to be absent to prevent inaccurate results. The Mohr method may be adapted to determine the total chlorine content of a sample by igniting the sample with calciumthen ferric acetate. We call this type of titration a precipitation titration.

This is the same example that we used in developing the calculations for a precipitation titration curve. What xrgentometric some example of the use of argentometric titration?

A comparison of our sketch to the exact titration curve Figure 9.

Methods based on precipitation of silver compounds I are called collectively argentometric methods. Quantitative chemical analysis 6th ed. Home Questions Tags Users Unanswered.

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Argentometric (silver nitrate) titrations overview

A second type of indicator uses a species that argentmoetric a colored complex with the titrant or the titrand. Solution There are two precipitates in this analysis: One of the earliest precipitation titrations—developed at the end of the eighteenth century—was the analysis of K 2 CO 3 and K 2 SO 4 in potash. The red arrows show the end points. This page was last edited on 5 Decemberat These methods are based on back titration of excess silver with standardized thiocyanate solution.

The stoichiometry of the reaction requires that. For example, after adding There are two precipitates in this analysis: Before precipitation titrimetry became practical, better methods for identifying the end point were necessary.

Before the end point, the precipitate of AgCl has a negative surface charge due to the adsorption of excess Cl —. Before the equivalence point the titrand, Cl —is in excess. The scale of operations, accuracy, precision, sensitivity, time, and cost of a precipitation titration is similar to those described elsewhere in this chapter for acid—base, complexation, and redox titrations. Chloride ions react with silver I ions to give the insoluble silver chloride:.

Sign up using Email and Password. The solution needs to be near neutral, because silver hydroxide forms at high pH, argentometrid the chromate forms H 2 CrO 4 at low pH, reducing the concentration of chromate ions, and delaying the formation of the precipitate.


The first type of indicator is a species that forms a precipitate with the titrant. Because this equation has two unknowns—g KCl and g NaBr—we need another equation that includes both unknowns. Because CrO 4 2— imparts a yellow color to the solution, which might obscure the end point, only a small amount of Argentometruc 2 CrO 4 is added. Ferric acetate removes phosphates.


The analysis for I — using the Volhard method requires a back titration. By using this site, you agree to the Terms of Use and Privacy Policy. Calculate pCl before the equivalence point by determining the concentration of unreacted NaCl.

Precipitation Titrations – Chemistry LibreTexts

A better fit is possible if the two points before the equivalence point are further apart—for example, 0 mL and 20 mL— and the two points after the equivalence point are further apart. The end point is found by visually examining the titration curve. Note See Table 9.

The pH also must be less than 10 to avoid the precipitation of silver hydroxide. By using our site, you acknowledge that you have read and understand our Cookie PolicyPrivacy Policyand our Terms of Service. Calcium acetate “fixes” free chlorine, precipitates fitrations, and titratuons the resultant solution.

A further discussion of potentiometry is found in Chapter The first reagent is added in excess and the second reagent used to back titrate the excess. Eosin tetrabromofluorescein is suitable for titrating against bromideiodideand thiocyanate anions, giving a sharper end-point than dichlorofluorescein.

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